However, she met Natasha in her apartment building, where Steve also resides, but Darcy doesn't know that Steve is Captain America, until she ends up getting promoted to Coulson's assistant. ummmm, there is a lot more I remember, but it doesn't really make sense in the order it's coming to my mind.
Oh, one scene is where during training Darcy spots Coulson, who is walking with a cane, and she runs after him so that she can tell him that one of the songs on her IPod (New York New York I think it was) was incorrect, because she copied it via record player and laptop speaker. However, the agents that went to copy it the same way were startled and somewhat afraid of a pig (hog?), and gramma Lewis chastised Darcy for not warning her that men in suits would randomly appear at her door to do the copying of the song.
Another scene is where Darcy is in the lobby coffee shop (at least I assume it was the lobby it didn't really specify) and two agents are talking about how Clint can't be trusted because he had been brain washed and so would eventually turn evil, when Darcy tazes him. Then tells him that he would need to fill out a form for 'being a dumbass in public', which then becomes an actual form.